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Creators/Authors contains: "Carroll, Alan"

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  1. Weathering, erosion, and sediment transport in modern landscapes may be investigated via direct observation of attributes such as elevation, relief, bedrock lithology, climate, drainage organization, watershed extent, and others. Studies of ancient landscape evolution lack this synoptic perspective, however, and instead must rely more heavily on downstream records of fluvial deposits. Provenance analysis based on detrital grain ages has greatly enhanced the utility of such records but has often focused broadly on regional to continental scales. This approach may overlook important details of localized watersheds, which could lead to significant misinterpretation of past sediment dispersal patterns. The present study, therefore, explores the impact of geographic and stratigraphic sampling density on detrital zircon provenance, based on a high-density investigation of U-Pb ages (N = 23, n = 4905) obtained from a narrow chronostratigraphic range (∼2 m.y.) within a relatively small (∼25,000 km2) area of an Eocene nonmarine sedimentary basin. Based on multi-dimensional scaling and DZmix modeling, these strata comprise seven distinct, approximately isochronous detrital zircon (DZ) chronofacies, defined as “. . . a group of sedimentary rocks that contains a specified suite of detrital zircon age populations” (Lawton et al., 2010). Four of these DZ chronofacies reflect long-distance transport from extrabasinal source areas. DZ chronofacies CO-1 and CO-2 are interpreted to derive from a primary sediment source in central Colorado (USA), corroborating previously proposed long-distance sediment transport via the Aspen paleoriver. DZ chronofacies ID-1 and ID-2 are interpreted to have been delivered to the basin from central Idaho by the Idaho paleoriver. In contrast, DZ chronofacies UT-1 and UT-2 are interpreted to reflect local drainage from the Uinta Uplift south of the basin, and DZ chronofacies WY-1 is interpreted to have been sourced from the Rawlins, Granite, and Sierra Madre uplifts to the north and east via the Toya Puki paleoriver. Lateral transitions between different DZ chronofacies in some cases occur over distances as little as 5 km, implying that depositional systems carrying sand from disparate watersheds directly competed to fill available basin accommodation. The results of this study reveal a high degree of complexity of Eocene rivers that converged on the Greater Green River Basin, indicating that their deposits contain a rich record of fine-scale landscape evolution across much of the Laramide foreland and Cordilleran orogen. These results illustrate the need for adequate sample density when assessing basin-scale provenance and offer a cautionary consideration for researchers using sandstone (and incorporated authigenic cement) in other nonmarine basins as the basis for paleoaltimetry or detrital thermochronology studies. 
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  2. Paleohydrologic proxy data and climate models show how and why eccentricity and precession influenced early Eocene hydroclimate. 
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  3. It has long been recognized that lakes can bury large amounts of organic carbon (CORG) in their sediment, with important consequences for conventional and unconventional petroleum resources and potentially for the global carbon cycle. The detailed distribution of lacustrine organic carbon through space and time is important to understanding its commercial and climatic implications, but has seldom been documented in detail. The Green River Formation offers a unique opportunity to improve this understanding, due to extensive Fischer assay analyses of its oil generative potential and to recently published radioisotopic age analyses of intercalat ed volcanic tuffs. Fischer assay analyses reveal distinctly different patterns of organic matter enrichment that correlate with different lacustrine facies associations. Histograms of oil generative potential for evaporative facies of the Wilkins Peak Member exhibit an approximately exponential distribution. This pattern is interpret ed to result from episodic expansion and contraction of Eocene Lake Gosiute across a low-gradient basin floor that experienced frequent desiccation. In contrast, histograms for fluctuating profundal facies of the upper Rife Bed of the Tipton Member and the lower LaClede Bed of the Laney Member exhibit an approximately normal or log normal distribution, with modes as high as 16–18 gallons per ton. This pattern is interpreted to reflect generally deeper conditions when the lake often intersected basin-bounding uplifts. Within the Bridger basin, burial of CORG was greatest in the south during initial Wilkins Peak Member deposition, reflecting greater rates of accommodation near the Uinta uplift. The locus of CORG burial shifted north during upper Wilkins Peak Member deposition, coincident with a decrease in differential accommodation. CORG burial during deposition of the upper Rife and lower LaClede Beds was greatest in the southeast, due either to greater accommodation or localized influx of river-borne nutrients. Average CORG burial fluxes are consistently ~4-5 g/m2 yr for each interval, which is an order of magnitude less than fluxes reported for small Holocene lakes in the northern hemisphere. Maximum rates of CORG burial during deposition of organic-rich mudstone beds (oil shale) were likely similar to Holocene lakes however. Deposition of carbonate minerals in the Bridger basin resulted in additional, inorganic carbon burial. Overall it appears that carbon burial by Eocene lakes could have influenced the global carbon cycle, but only if synchronized across multiple lake systems. 
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  4. Lacustrine strata are often among the highest-resolution terrestrial paleoclimate archives available. The manner in which climate signals are registered into lacustrine deposits varies, however, as a function of complex sedimentologic and diagenetic processes. The retrieval of reliable records of climatic forcing therefore requires a means of evaluating the potential influence of changing sedimentary transfer functions. Here, we use high-resolution X-ray fluorescence core scanning of the Wilkins Peak Member of the Green River Formation to characterize the long-term evolution of transfer functions in an ancient lacustrine record. Our analysis identifies a shift in the frequency distribution of Milankovitch-band variance between the lower and middle Wilkins Peak Member across a range of temporally calibrated elemental intensity records. Spectral analysis of the lower Wilkins Peak Member shows strong short eccentricity, obliquity, precession, and sub-Milankovitch−scale variability, while the middle Wilkins Peak Member shows strong eccentricity variability and reduced power at higher frequencies. This transition coincides with a dramatic decline in the number and volume of evaporite beds. We attribute this shift to a change in the Wilkins Peak Member depositional transfer function caused by evolving basin morphology, which directly influenced the preservation of bedded evaporite as the paleolake developed from a deeper, meromictic lake to a shallower, holomictic lake. The loss of bedded evaporite, combined with secondary evaporite growth, results in reduced obliquity- and precession-band power and enhanced eccentricity-band power in the stratigraphic record. These results underscore the need for careful integration of basin and depositional system history with cyclostratigraphic interpretation of the dominant astronomical signals preserved in the stratigraphic archive. 
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  5. Lacustrine chemical sediments of the Wilkins Peak Member, Eocene Green River Formation potentially preserve paleoclimate information relating to the conditions of their formation and preservation within the lake basin during the Early Eocene Climatic Optimum. The Green River Formation comprises the world’s largest sodium-carbonate evaporite deposit in the form of trona (Na2CO3⋅NaHCO3⋅2H2O) in the Bridger sub-basin and nahcolite (NaHCO3) in the neighboring Piceance Creek basin. Modern analogues suggest that these minerals necessitate the existence of an alkaline source water. Detrital provenance geochronometers suggest that the most likely source for volcanic waters to the Greater Green River Basin is the Colorado Mineral Belt, connected to the basin via the Aspen paleo-river. We tested the hypothesis that magmatic waters from the Colorado Mineral Belt could have supplied the Greater Green River Basin with the alkalinity needed to precipitate sodium-carbonate evaporites that are preserved in the Wilkins Peak Member by numerically simulating the evaporation of modern soda spring waters from northwestern Colorado at various temperature and atmospheric pCO2 conditions. We compare the resulting simulated evaporite sequences of the modern soda spring waters to the mineralogy preserved within the Wilkins Peak Member. Simulated evaporation of Steamboat Springs water produces the closest match to core observations and mineralogy. These simulations provide constraints on the salinities at which various minerals precipitated in the Wilkins Peak Member as well as insights into the regional temperature (>15ºC for gaylussite and trona; >27º for pirssonite and trona) and pCO2 conditions (<1200ppm for gaylussite and trona) during the EECO. 
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  6. The Wilkins Peak Member (WPM) of the Green River Formation in Wyoming, USA, comprises alternating lacustrine and alluvial strata that preserve a record of terrestrial climate during the early Eocene climatic optimum. We use a Bayesian framework to develop age-depth models for three sites, based on new 40Ar/39Ar sanidine and 206Pb/238U zircon ages from seven tuffs. The new models provide two- to ten-fold increases in temporal resolution compared to previous radioisotopic age models, confirming eccentricity-scale pacing of WPM facies, and permitting their direct comparison to astronomical solutions. Starting at ca. 51 Ma, the median ages for basin-wide flooding surfaces atop six successive alluvial marker beds coincide with short eccentricity maxima in the astronomical solutions. These eccentricity maxima have been associated with hyperthermal events recorded in marine strata during the early Eocene. WPM strata older than ca. 51 Ma do not exhibit a clear relationship to the eccentricity solutions, but accumulated 31%−35% more rapidly, suggesting that the influence of astronomical forcing on sedimentation was modulated by basin tectonics. Additional high-precision radioisotopic ages are needed to reduce the uncertainty of the Bayesian model, but this approach shows promise for unambiguous evaluation of the phase relationship between alluvial marker beds and theoretical eccentricity solutions. 
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  7. Mineralogy, petrographic textures, and sedimentary structures from the world’s largest trona deposit, the Wilkins Peak Member (WPM) of the early Eocene Green River Formation (GRF), Bridger subbasin, Wyoming, provide key data about depositional conditions and paleoenvironments. The 250 m-long WPM interval in the Solvay S-34-1 drill core analyzed in this study contains a detailed record of sedimentation in the Bridger subbasin at the deepest area of a hydrologically-closed basin during peak Cenozoic atmospheric CO2 concentrations. Large accumulations of trona (Na3(HCO3)(CO3)·2H2O), shortite (Na2Ca2(CO3)3), northupite (Na3Mg (CO3)2Cl), and halite (NaCl; now replaced by trona), occur in the lower half of the WPM. Modern saline lake environments such as Lake Magadi, Kenya, and the Dead Sea, Israel-Jordan, are useful analogues for interpreting paleolake conditions associated with evaporite deposition in the Solvay S-34-1 core. Solvay saline lake deposits are organized into meter-scale shallowing-upward successions, beginning with (1) oil shale overlain by (2) trona, in places interbedded with oil shale, followed by (3) peloidal dolomite grainstone and/or silty dolomitic mudstone, and (4) massive mudstone with disruption features or desiccation cracks, and/or siliciclastic sandstone with ripple cross-stratification. Based on observations of modern hypersaline lake environments, WPM evaporite deposition at the basin depocenter is interpreted to be controlled by inflow water composition and volume, evaporative concentration, and seasonally-driven lake temperature fluctuations, resulting in recurrent patterns in evaporite mineralogies and textures. 
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  8. null (Ed.)